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Atmospheric storage tank normal venting based on API Std 2000 6th edition, Nov 2009 has been discussed in "Tank Normal Venting Rate Estimation Using Latest Method As in API Std 2000". Ankur, an experience engineer in Chemical industry, actively involved in CheResource Forum, has take his effort and time to program it in Microsoft Excel spreadsheet. Thanks to Ankur.

Insulation type and recommended thermal conductivity have also been included in the spreadsheet for easy reference. The insulation type and thermal conductivity as follow :

Products contain volatile components or dissolved gases or flashing products may result adddtional volatile component / gases / vapor. This amount will increase the outbreathing rate.

Products stored at temperature above 40 degC or its vapor pressure higher than 5.0 kPa, products evaporation rate shall be added into outbreathing rate.


Read and download spreadsheet in "Tank Normal Venting Rate Estimation Using Latest Method As in API Std 2000".

* If you find any error or improvement,  please inform us.
**If you have any useful program and would like to share within our community, please send to me.

Related Post

• Tank Normal Venting Rate Estimation Using Latest Method As in API Std 2000
• Tank Venting - API Std 2000 (Nov 2009) - Revised method and Old Method in ANNEX A
• Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 (Annex A)
• Tank Normal Venting Rate Estimation Using Siddhartha Equation
• Find Latitude & Longitude Using GOOGLE MAP

Liquid in tank truck or storage tank may spill on the ground. Wind blowing, solar and ground surface heating will results evaporation of spilled liquid. The evaporation rate is one of the key information required during design phase for consequence analysis and preparation of emergency handling measures. What is the quick way to estimate evaporation rate ?

Evaporation rate from spilled liquid subjects to several factors such as :

Methanol with vapor pressure (VP) of 125 mmHg and MW of 32.04 stored at 25 degC in a 25,000 US gal tank (10 ft diameter). Overfilled methanol results spillage of 1,000 US gal of methanol spread in the diked area (100ft x 40 ft) which contain 8 identical tanks. Assuming wind speed is 1.5 m/s, estimate evaporation rate.

V = 1000 /  7.48051948 ft³

A_wc = 4,050 ft²

A_dike = 3371.7 ft²

Since A_wc is larger than A_dike, entire dike area will be occupied by spilled liquid.


Inputs

U =1.5 m/s
MW =32.04
A =3371.7 ft²
VP =125 mmHg
T =25 + 273.15 = 298.15 K

Evaporation rate
Ref : "Risk management program guidance for offsite Consequence Analysis", US EPA, Apr 1999

Related Post

• Tank Normal Venting Rate Estimation Using Latest Method As in API Std 2000
• Tank Venting - API Std 2000 (Nov 2009) - Revised method and Old Method in ANNEX A
• Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 (Annex A)
• Tank Normal Venting Rate Estimation Using Siddhartha Equation
• Two Useful Equations For Flow Conversion between Air - Vapor & Actual - Standard
• Relate NORMAL to STANDARD Volumetric Flow
• Relate NORMAL to ACTUAL Volumetric Flow 
• Environment related 

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Liquid product like Chemical, condensate, etc is commonly stored in fixed roof vertical cylindrical tank. Inert gas blanketing system is provided to avoid air and moisture contact and contaminate liquid product. Liquid movement by content filling (pump-in) or emptying (pump out) and weather changes (ambient heating or cooling) will results internal pressure increase (overpressure) or decrease (vacuum) in the tank. Thus, a protecting system providing inbreathing or outbreathing gas is provided to maintain a constant pressure in the tank.

Emptying (pump-out) and ambient cooling will lead to normal inbreathing. General equation to determine inbreathing flow :

V_in,air = Total inbreathing in Nm3/h (Air)

V_pe = Pump-out or emptying in m3/h

V_tk = Tank capacity in m3

R_i = Insulation reduction factor
C = Factor subject to vapor pressure, average temperature and latitude (see Table 1)

Find Latitude & Longitute Using GOOGLE MAP

Filling (pump-out) and ambient heating will lead to normal outbreathing. General equation to determine outbreathing flow :

V_out,air = Total Outbreathing in Nm3/h (Air)

V_pf = Pump-out or filling in m3/h

V_tk = Tank capacity in m3
R_i = Insulation reduction factor

Y = Factor subject to latitude (see Table 2)

 
L_in = Insulation thickness in m
Lamda_in = Insulation thermal conductivity in w/mK

The following method is the latest method used in API Std 2000, ISO 28300 & EN 14015. Nevertheless, API Std 2000 (6th edition) still maintaining the old method in ANNEX A as an alternative approach in determining normal venting rate. Comparison and recommendation can be found in "Tank Venting - API Std 2000 (Nov 2009) - Revised method and Old Method in ANNEX A".

In determining normal tank venting rate per ANNEX A, designer can estimate tank venting rate from a table. Siddhartha has presented an equation to predict tank venting based on simple correlation, as discussed in " Tank Normal Venting Rate Estimation Using Siddhartha Equation". JoeWong has further proposed a new correlation as discussed in "Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 Data" with better accuracy.

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Liquid product like Chemical, condensate, etc is commonly stored in fixed roof vertical cylindrical tank. Inert gas blanketing system is provided to avoid air and moisture contact and contaminate liquid product. Liquid movement by content filling (pump-in) or emptying (pump out) and weather changes (ambient heating or cooling) will results internal pressure increase (overpressure) or decrease (vacuum) in the tank. Thus, an overpressure and vacuum protecting system providing inbreathing or outbreathing gas is provided to maintain a constant pressure in the tank.

There are several recommended practice (RP) and standard (STD) are available to guide engineers in designing and specifying venting / relief load from a storage tank.

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In determining normal tank venting rate, API STD 2000, (edition 1999) allows designer to estimate tank venting rate from a table. Siddhartha has presented an equation to predict tank venting based on simple correlation, as discussed in " Tank Normal Venting Rate Estimation Using Siddhartha Equation". JoeWong has further proposed a new correlation as discussed in "Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 Data" with better accuracy.

The methodology in determining normal inbreathing and outbreathing rate are different between API Std 2000 and ISO 28300 / EN14015. Groth Corporation, a well known Pressure-Vaccum relief valve manufacture has conducted a study to compare the API Std 2000 and ISO 28300 / EN14015. A few differences are identified :

One of the interesting findings in the study was the normal inbreathing and outbreathing comparison betweeen API STD 2000 and ISO 28300/EN 14015.

(Click image for large image)
Source : Groth Corporation

Details can be found in " Introduction and ISO 28300 Presentation". Above study was comparing API STD 2000, revision 1999 and latest ISO 28300 / EN 14015. API has recently released latest API STD 200, last NOV 2009. One of the main changes was synchronizing methodology between API STD 2000 rev. Nov 2009 and latest ISO 28300 / EN 14015. 



Opinions
Previous method used in API STD 2000 still maintain in Annex A as "Alternative Calculation of normal venting requirements". This annex provides a calculation approach that may be used to design protection systems for the normal venting requirement of petroleum storage tank.

Above finding indicates minor difference in outbreathing rate between API STD 2000 and ISO 28300 / EN 14015. Both methods are acceptable for estimating outbreathing (in main text and annex A). However, present inbreathing method (as in annex A) consistently lower compare to revised method. It is always take extra precaution when you used annex A for estimating inbreathing rate.

You may be working on ongoing project priors to revision of API STD 2000 (NOV 2009). Following standard implementation spirit, you may continue to use old revision. However, it is always advisable to refer to latest API STD 2000 from safety and integrity aspect.

You may work on revamping or debottlenecking of existing plant, extra precaution shall be  taken. Whenever you have modification or new requirement to existing tank, you may have to comply to latest API STD 2000 (NOV 2009) even thought your existing tank was designed and fabricated to old revision of API STD 2000.

Related Post

• Tank Normal Venting Rate Estimation Using Latest Method As in API Std 2000
• Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 Data
• Tank Normal Venting Rate Estimation Using Siddhartha Equation
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Flare is commonly installed in oil and gas process plant to burn hydrocarbon and/or toxic gas to avoid formation of combustible mixture, to minimize green house effect (GHE), to minimize health hazards to personnel on site, etc. There are several earlier posts related to Flare :

Flare collection header is normally "NO flow" as most (if not all) devices connected to flare header are non-discharging fluid into flare system. Among all are pressure relief valve (PRV), blowdown valve (BDV), overpressure dump valve (PCV), etc. All these devices are kept as close position during normal plant operation and will only open in the event of overpressure, emergency situation i.e. fire, runaway reaction, plant shutdown/blowdown for maintenance.

On the flare tip end, it is open to atmosphere. it is very likely that atmosphere air contain oxygen ingress and stay into flare collection header. PRV/BDV/PCV passing and open on demand will discharge large quantity of hydrocarbon gas into flare collector header filled with air and create combustible mixture, as this combustible mixture travel along flare header and reach flare tip which equipped with flare pilot, combustible mixture will be ignited and potentially created flash back to the flare header and flare knock-out drum (KOD). Subject to flare header capacity and mechanical integrity, large flash back lead to severe internal pressure act on the piping & vessel and vapor wave results severe vibration and movement of structure, this potential lead to catastrophe failure of flare collection system. Therefore a flare header is sweep or purge with fuel gas or inert gas i.e. Nitrogen.

Advantages using inert gas compare to fuel gas as purge gas

i) Environment & Green House Effect (GHE)
IG : Inert gas has NO impact to environment
FG : Burn fuel gas in atmosphere generate Carbon Dioxide (CO2) which contributes to increase of Co2 content in atmosphere and increases Green House Effect (GHE)

ii) Burn back damage flare tip - reduce life span of flare tip
IG : Inert gas do not burn. NO burn back and potential damage of flare tip.
FG : Potential FG burn back damage flare and shorten flare tip life span.

iii) High OPEX avoid Burn back
IG : NO burn back. Minimum purge rate and low OPEX.
FG : Potential burn back lead to high purge rate (potential 10 times higher than purge rate of IG) and high OPEX

iv) Visible Flame
IG : Inert gas do not burn. No flame present.
FG : FG continuous burn and continuous visible flare at flare tip. Potential create uneasy situation in environment sensitive area.

v) Smoke Flaring
IG : Inert gas do not burn. No smoke flaring issue.
FG : Burning heavy FG lead to smoke flaring. Potential create uneasy situation in environment sensitive area. Increase likelihood of unburnt component and impact on environment.

vi) Steam injection for smokeless flaring
IG : Inert gas do not burn. No smoke flaring issue.
FG : Burning heavy FG lead to smoke flaring. Steam injection to reduce/eliminate smoke flaring. This increases CAPEX (additional steam injection facilities) and OPEX (steam loss).

vii) Radiation
IG : Inert gas do not burn. No additional radiation.
FG : Fuel gas burn lead to increase of radiation level (on top of solar radiation) to personnel working near flare stack.

Disadvantages using inert gas compare to fuel gas as purge gas

a) Fuel Gas Readily Available in Plant
IG : Required Nitrogen generator or use of Liquid Nitrogen and evaporator. Additional CAPEX and OPEX.
FG : Fuel gas readily available in plant. Minimum CAPEX and OPEX. Some plant generate hydrocarbon gas which shall be disposed off. This gas is readily serve as purge gas and inccur NO cost.

b) Inert Gas Cloud
IG : Flare system purge with inert gas, entire flare system is filled with IG gas (which potential heavier than air). Once any PSV/BDV open and release large amount of gas into flare header, it will "push" IG release through the flare tip. Heavy IG (compare to air) will sink create a IG gas cloud near plant. This is potential fatal thread (suffocation) to personnel on site.
FG : Continuous flaring lead to no or nearly no potential of gas present in atmosphere

c) Unburnt hydrocarbon gas emission
IG : PRV/BDV/PCV leak or passing lead to low heating value mixure (less than 200 btu/ft3) which is non-combustible. Release of hydrocarbon gas into atmosphere directly has more GHE impact than burning it. For example 1 mol of methane create 1 mol of CO2 if it is burnt. 1 mol of methane create 20-21 mol of equivalent CO2 if it unburnt.
FG : Continuous flaring lead to no or nearly no unburnt gas in atmosphere

d) Combustible Cloud lead to Instant Ignition
IG : Slowly hydrocarbon gas emission to atmosphere and built-up of combustible mixture in the plant, once the heating value for auto-ignition is reached, the combustible mixture potentially ignited. Its impact is just like a explosion and potential thread to personnel and surrounding facilities.
FG : Continuous flaring lead to no or nearly no unburnt gas in atmosphere

Concluding remark
Inert gas purging is normally understood as clean, low CAPEX, low OPEX, etc and regards as most likely candidate for flare purging. However, the associated SAFETY related issue may needs additional attention and focus. All...use inert gas wisely...

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• CO2 related topics...
  
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Earlier post "Heat Radiation For Pain & Blistering Threshold" and "Personnel Exposure Time For Heat Radiation" have discussed the heat radiation level lead to plant personnel pain and blistering threshold within an exposure time. Heat radiation design criteria for personnel exposure has been proposed for continuous and emergency exposure. Flare radiation run using software i.e. FLARESIM or calculation using Brzustowski and Sommer method, heat radiation level will be estimated and presented. For equipment, instrument, piping, painting, steel structure, etc expose to flare radiation will experienced increase temperature.

How shall a heat radiation level relates to temperature ?

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Earlier post "Heat Radiation For Pain & Blistering Threshold" has briefing discussed about the exposure time for heat radiation level which lead pain and blister threshold. Equations have been proposed in order to link between exposure time for dedicated heat radiation. Example, with heat radiation of 6.3 kW/m2 (2 000 Btu/h·ft2), the pain threshold is reached in 8 s and blistering occurs in 20 s.

Maximum allowable personnel exposure time to particular heat radiation level proposed in API RP 521 (previous revision - 1997) and API Std 521 (latest revision - May 2008) are marginally different. Detail list out as follow

Heat Radiation (kw/m2)	API Rp 521 (March 1997)	API Std 521 (May 2008)
9.45	Exposure must be limited to a few (approx. six) seconds, sufficient for escape only. May consider tower or structure provide some degree of shielding.	Required urgent emergency action. Radiation shielding and/or special protective apparel (e.g. a fire approach suit) required
6.31	Emergency actions lasting up to 1 minutes without shielding but with appropriate clothing.	Emergency actions lasting up to 30s without shielding but with appropriate clothing.
4.73	Emergency actions lasting up to several minutes without shielding but with appropriate clothing.	Emergency actions lasting 2 min to 3 min without shielding but with appropriate clothing.
1.58	personnel with appropriate clothing can be continuously exposed	personnel with appropriate clothing can be continuously exposed

Above listing shows that latest API Std 521 has more stringent requirement compare to previous revision (1997), specifically for 6.31 and 4.73 kW/m2. The maximum allowable exposure time limit have been reduced. Continuous exposure limit remain unchanged.

Emergency Exposure
Maximum allowable exposure heat radiation of 6.31 and 4.73 kW/m2 (during emergency scenario) have been used as criteria in determining sterile area, an area around flare stack which no personnel shall be around without any personnel protective apparel. For conservative design and/or expect potential increase in flaring rate in future, a limit of 4.73 kW/m2 may be used. For common design, heat radiation limit of 6.31 kW/m2 is widely used. In general, maximum allowable heat radiation of 9.46 kW/m2 will be limited at the flare stack base where personnel may access to sterile area with proper personnel protective apparel.

Continuous Exposure
For continuous exposure, operator is assumed wearing appropriate clothing in a plant. Heat radiation at any location shall be limited to 1.58 kW/m2.

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Recommended :Flare is commonly installed in oil and gas process plant to burn hydrocarbon and/or toxic gas to avoid formation of combustible mixture, to minimize green house effect (GHE), to minimize health hazards to personnel on site, etc. Flaring hydrocarbon gas may generate carbon dioxide & water for complete combustion and soot (contribute to smokeless level) & unburnt components (contributes to toxic environment) for incomplete combustion. Besides, heat and noise are generated and radiated and transmitted around the flare tip.

Heat radiated from flare may transmitted in sphere form around the flare tip. Along the transmission, the energy is distributed in sphere form and this lead to reduction in heat radiation level (heat flux, kW/m2). Personnel or equipment along the transmission path will expose to this heat radiation. Personnel or equipment closer to flare tip will experience higher heat radiation level.

With studies conducted by Stoll and Greene (1958), following graph relate heat radiation versus time for Pain threshold and Blister threshold. With heat radiation of 6.3 kW/m2 (2 000 Btu/h·ft2), the pain threshold is reached in 8 s and blistering occurs in 20 s.


The following equation derived from above graph and can be used to relates heat radiation with time for pain and blister thresholds.

Pain threshold :

Blister threshold :

where :
q = heat radiation (kW/m2)
t = time (seconds)


Ref :
(i) A. M. STOLL and L. C. GREEN, The Production of Burns by Thermal Radiation of Medium Intensity, Paper Number 58-A-219, American Society of Mechanical Engineers, New York, 1958

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• Assess AIV with "D/t-method" with Polynomial PWL Limit Line
• Model Fix Pressure Device in FLARENET
• Several Criteria and Constraints for Flare Network - Process
• Several Criteria and Constraints for Flare Network - Piping
• Provide More than One Flare KOD in SERIES

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As discussed in earlier post "Estimate Wind Speed At Flare Tip At Different Height", correct wind speed at flare tip (elevated flare) is important in order to obtain correct estimate of radiation level and unburnt component concentration at downwind location, determination of minimum vapor flow to avoid flame-out and performance of pilots. A rather complicated equations may be used to estimate wind speed at different height.

This will present a rather simple relation to estimate the wind speed. The following equation may be considered.

Where
U_Z = Wind speed at Z m at return duration of t₀ hour (m/s)
U₀ = Wind speed at specified height of 10m at return duration of t₀ hour (m/s)
t₀ = Wind speed at return duration i.e. 60 minutes, 1 minutes, etc
Z = Flare stack height (m)
K = Field data derived parameter (may use 0.125)

Example :
A flare stack with height of 200m, expose to wind speed (at 60 minutes return duration) of 10 m/s measured at 10m from grade. Determine wind speed at flare tip if the return duration stay as 60 minutes.

Solution (a)
Z = 200 m
U₀ = 10 m/s


U_Z = 14.54 m/s
Wind speed at flare tip with return duration stay as 60 minutes = 14.54 m/s

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• Model Fix Pressure Device in FLARENET
• Several Criteria and Constraints for Flare Network - Process
• Several Criteria and Constraints for Flare Network - Piping
• Provide More than One Flare KOD in SERIES

Flare is commonly installed in oil and gas process plant to burn hydrocarbon and/or toxic gas to avoid formation of combustible mixture, to minimize green house effect (GHE), to minimize health hazards to personnel on site, etc. There are several earlier posts related to Flare :

• Quick Estimate Flare Stack Diameter
• Estimate Subsonic Flare Tip Pressure Drop With Graph Derived Correlation
• Quick Estimate Flare Tip Pressure Drop
• Flare Tip Type Quick Selection Chart
• ANSI/API Std 537 / ISO 25457 2nd edition, Dec 2008 is Released
• Guideline on Quick Determination of Flare Stack Support Type
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Wind speed affect flare performance
Wind speed affects flare performance at least in few ways :

1. Wind drag flame to downwind, lower the flame center and radiation level of downwind receptor
2. Wind carry unburnt component to downwind
3. Wind potential put-off flame on flare under low gas flow and pilot

Therefore, correct wind speed at flare tip (elevated flare) is important in order to obtain correct estimate of radiation level and unburnt component concentration at downwind location, determination of minimum vapor flow to avoid flame-out and performance of pilots.

Wind speed change with flare height
One of characteristic of wind speed is wind speed increase with height from grade. Thus, higher the flare stack, flare tip will expose to higher wind speed. Generally wind map will be obtained from local authority or organization. The wind map may be measured at specific height i.e. 10m from grade.

In case flare stack height is different than wind speed at specific height, how shall an engineer determine wind speed flare tip ?

Corrected wind speed (without return duration correction)


Where
U_Z = Wind speed at Z m at return duration of t0 hour (ft/s)
U₀ = Wind speed at specified height of 10m at return duration of t0 hour (ft/s)
t₀ = Wind speed at return duration i.e. 60 minutes, 1 minutes, etc
Z = Flare stack height (ft)

Corrected wind speed (with return duration correction)



Where
t = Wind speed at return duration i.e. 60 minutes, 1 minutes, etc (different than t₀ )

Example :
A flare stack with height of 200m, expose to wind speed (at 60 minutes return duration) of 10 m/s measured at 10m from grade. Determine wind speed at flare tip if (a) the return duration stay as 60 minutes (b) return duration change to 1 minute.

Solution (a)
Z = 200 m = 200 x 32.8 ft
U_Z = 10 m/s = 10 x 32.8 ft/s



U_Z = 41.7 ft/s = 12.7 m/s
Wind speed at flare tip with return duration stay as 60 minutes = 12.7 m/s


Solution (b)


u_Z,t = 44.8 ft/s = 13.66 m/s

Wind speed at flare tip with return duration at 1 minutes = 13.66 m/s


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• Assess AIV with "D/t-method" with Polynomial PWL Limit Line
• Model Fix Pressure Device in FLARENET
• Several Criteria and Constraints for Flare Network - Process
• Several Criteria and Constraints for Flare Network - Piping
• Provide More than One Flare KOD in SERIES

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Earlier post "Tank Normal Venting Rate Estimation Using Siddhartha Equation", Siddhartha equation has been presented. The proposed equations are rather simple and easy to use.

Following post will discuss the comparison between prediction Siddhartha equation and API Std 2000 data. New equations with better accuracy are proposed.

Thermal Inbreathing
From earlier post, thermal inbreathing flow cause by ambient cooling can be determined based on following equations :

If V_tank less than or equal to 3500 m3,

If V_tank more than 3500 m3,


where
Q_{thermal in,air} = Thermal inbreathing in Sm3/h (Air)
V_tank = Tank capacity in m3

To convert Sm3/h to Nm3/h, divide inbreathing / outbreathing flow with a factor of 1.055. Refer "Relate NORMAL to STANDARD Volumetric Flow"

The error difference for thermal inbreathing between above equations and API Std 2000 data is about :