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Chemical Process Technology

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Chemical & Process Technology

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Tuesday, March 9, 2010

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Liquid product like Chemical, condensate, etc is commonly stored in fixed roof vertical cylindrical tank. Inert gas blanketing system is provided to avoid air and moisture contact and contaminate liquid product. Liquid movement by content filling (pump-in) or emptying (pump out) and weather changes (ambient heating or cooling) will results internal pressure increase (overpressure) or decrease (vacuum) in the tank. Thus, a protecting system providing inbreathing or outbreathing gas is provided to maintain a constant pressure in the tank.

Inbreathing
Emptying (pump-out) and ambient cooling will lead to normal inbreathing. General equation to determine inbreathing flow :

Vin,air = Vpe + CVtk0.7 Ri

where
Vin,air = Total inbreathing in Nm3/h (Air)
Vpe = Pump-out or emptying in m3/h
Vtk = Tank capacity in m3
Ri = Insulation reduction factor
C = Factor subject to vapor pressure, average temperature and latitude (see Table 1)

Table 1 : C-factor for Inbreathing
Latitude Vapor Pressure
Hexane
or similar
Higher than hexane
or unknown
Average Storage Temperature  (oC)
< 25 >=25 < 25 >=25
Below 42o 4 6.5 6.5 6.5
42o to 58o 3 5 5 5
Above 58o 2.5 4 4 4

Find Latitude & Longitute Using GOOGLE MAP


Outbreathing
Filling (pump-out) and ambient heating will lead to normal outbreathing. General equation to determine outbreathing flow :

Vout,air = Vpf + YVtk0.9 Ri

where
Vout,air = Total Outbreathing in Nm3/h (Air)
Vpf = Pump-out or filling in m3/h
Vtk = Tank capacity in m3
Ri = Insulation reduction factor
Y = Factor subject to latitude (see Table 2)


Table 2 : Y-factor for Outbreathing
Latitude Y-factor
Below 42o 0.32
42o to 58o
0.25
Above 58o 0.2

Special notes :
i) If products contain volatile components or dissolved gases or flashing products, perform flashing calculation to estimate quantity of volatile component / gases / vapor. This amount shall be added into outbreathing rate.

ii) If products stored temperature above 40 degC or its vapor pressure higher than 5.0 kPa, products evaporation rate shall be added into outbreathing rate.

iii) Quick check on plant latitude, check out in "Find Latitude & Longitute Using GOOGLE MAP"

Determination of  Ri = Insulation reduction factor

If no insulation, 
Ri = 1

If fully insulated including Shell and roof,
Ri = Rin = (1 + h x Lin / Lamdain)-1
If partial insulated,

Ri = Rinp
Ri = (Ainp / ATTS).Rin + [1-(Ainp / ATTS)]

 
Lin = Insulation thickness in m
Lamdain = Insulation thermal conductivity in w/mK
h =Inside heat transfer coefficient in w/m2K  [4 w/m2K is commonly assumed]
Ainp = Insulated surface area of tank in m2
ATTS = Total tank surface area (shell + roof) in m2

Concluding remarks
The following method is the latest method used in API Std 2000, ISO 28300 & EN 14015. Nevertheless, API Std 2000 (6th edition) still maintaining the old method in ANNEX A as an alternative approach in determining normal venting rate. Comparison and recommendation can be found in "Tank Venting - API Std 2000 (Nov 2009) - Revised method and Old Method in ANNEX A".

In determining normal tank venting rate per ANNEX A, designer can estimate tank venting rate from a table. Siddhartha has presented an equation to predict tank venting based on simple correlation, as discussed in " Tank Normal Venting Rate Estimation Using Siddhartha Equation". JoeWong has further proposed a new correlation as discussed in "Tank Thermal Breathing - Proposed Equation Correlate API Std 2000 Data" with better accuracy.


Ref :
i) API Std 2000 "Venting Atmospheric and Low-Pressure Storage Tanks", 6th Edition, Nov. 2009
ii) ISO 28300 "Petroleum. petrochemical and natural gas industries -  Venting Atmospheric and Low-Pressure Storage Tanks"
iii) EN 14015 "Specification for the design and manufacture of site built, vertical, cylindrical, flat-bottomed, above ground, welded, steel tanks for the storage of liquids at ambient temperature and above "


**********************************

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